Researchers achieved 1,270 Wh/L in an anode-free lithium metal battery
postech.ac.kr113 points by giuliomagnifico 3 months ago
113 points by giuliomagnifico 3 months ago
This is only relevant for those deeply involved in fundamental or early-stage battery research.
An energy density of 1270 Wh/L is indeed roughly double what is currently found in top-tier electric vehicles. However, as with many battery research avenues, it is not viable on a practical level unless a major breakthrough is discovered in addition.
Here is a list of all the issues that must be resolved before such battery technology is viable for commercial use.
It only lasts about 100 charge cycles before degrading to 80% capacity, which is not sufficient for commercial use. LiFePO4 reaches this after a minimum of 3000 cycles.
It uses silver. In addition to this likely being a deal-breaker for mass production, the paper probably downplays the mass loading of silver required to maintain that 99.6% efficiency.
Anode-free batteries have zero excess lithium. Every time you charge/discharge, you lose a tiny fraction of lithium to side reactions. The paper claims a Coulombic Efficiency of 99.6%. The fact that they hit ~82% suggests the degradation is severe and inevitable without a massive reservoir of extra lithium, which defeats the "energy density" gain.
Density suppression for 100 cycles is not proof of safety. Dendrites often grow slowly and trigger short circuits later in life (cycle 200+).
There is also the known problem with pouch cells and significant volume change ("breathing"). The paper quotes volumetric density including packaging, but does it account for the swelling that happens after 50 cycles? Often, these cells puff up like balloons, rendering them unusable in a tight battery pack.
They tested at 0.5C (2-hour charge). Fast charging (15-20 mins) typically destroys lithium metal anodes instantly by causing rapid dendrite growth. This technology is likely limited to slow-charging applications.
Finally, there is no mention of temperature effects on performance.
I don’t mean to be negative, and research like this is extremely important. But this research paper is not properly framed. It’s like an archaeologist finding a buried house and extrapolating that this could mean we found an entire city! Why can’t we just say that the archaeologist found an interesting house?
If all four of the battery breakthrough articles on that page actually worked in a product, battery performance would be far higher than it is now. It seems to be possible to trade off charging rate, Wh/L, Wh/Kg, number of cycles, and safety. Any article that doesn't give all the stats is deceptive.
It's progress. The trouble is reading about it through the hype department at the university's PR operation.
> hype department
Yes but:
It's signal that battery tech will maintain its cost-learning-curve for some time to come.
It'll be noteworthy, to me, once these announcements start to trail off.
all matter in the universe carries a charge, so the list of potential battery materials candidates, is everything. also, everything that isnt something has energy passing through it, so even nothing, is usefull.
For comparison gasoline has about 9000 Wh/L of raw chemical energy, of which maybe 30-40% gets converted to useful work.
https://en.wikipedia.org/wiki/Energy_density
Gunpowder is 4-10 times less energy dense than gasoline. The difference is that gunpowder includes fuel and oxygen-producing substances, much like most of Li-ion batteries.
This thing is in gunpowder energy density range.
ICE engines outsource half of the reactants to the atmosphere, so this comparison isn't as useful as it appears at first.
Batteries can make use of the atmosphere as well (eg aluminum air batteries/ or venting hydrogen in lead acid batteries) although I don’t know of any rechargeable chemistries off hand that use environmental oxygen. All that to say the trick is available for batteries even if the best current chemistries by mass density don’t make use of it.
One I'm familiar with (but don't know deeply about) is Iron-air batteries [1]. Form Energy [2], an interesting grid-storage startup uses them. They're not energy-dense whatsoever, but very cheap, which makes them economical for that application.
[1]: https://en.wikipedia.org/wiki/Metal%E2%80%93air_electrochemi...
30…40% is very ideal number, 15…25% is often the reality.
A good hybrid can do very well. Presumably by keeping the engine in exactly its sweet spot and designing aggressively for that. BYD for example claims 46% thermal efficiency. [0]
Yes, hybrids are much more efficient especially in city driving, not so much on highway. I used to drive a Prius back in the day.
>"To address these issues, the research team adopted a dual strategy combining a Reversible Host (RH) and a Designed Electrolyte (DEL). The reversible host consists of a polymer framework embedded with uniformly distributed silver (Ag) nanoparticles,
guiding lithium to deposit in designated locations rather than randomly
. In simple terms, it acts like a dedicated parking lot for lithium, ensuring ordered and uniform deposition."
(I'm wondering if some process like this -- might one day replace (or supplement) photolithography for creating chips/IC's...)
> the battery retained 81.9% of its initial capacity after 100 cycles
That's really terrible.
It's interesting, but 20% loss after 100 cycles is just not great. NMC gets that at near 1000 cycles. LFP gets that at near 5000 cycles.
Seemingly adequate for certain drone applications like in Ukraine. They may only need a couple charge cycles, and 4x the capacity is huge.
20% loss isn't too bad if you start out at double the capacity though.
My first thought was put the new cells in aircraft, then cheap cars finally grid storage
That actually could make sense especially with a good recycling program. Swap the packs every flight and recycle anything that falls below standards.
A good recycling program sounds like a tall order. I'm seeing Silver nanoparticles (heavy metal) and multiple things that react violently with water.
I'm always skeptical of any idea that ends with a bespoke industrial-scale recycling process. People tend to massively underestimate the complexity of recycling, especially at scale.
In general, bespoke recycling processes can make sense, especially if you manage to design the items to recycle with the recycling process in mind. There are several types of goods where this is put into practice (paper, compounds like TetraPak packages, various polymer plastics). Not sure about all the differrent types of batteries, though.
We struggle to recycle normal batteries without injuring or killing people. Lead-acid batteries contain literal plates of lead oxides, and we can't manage to keep that out of the water supply! I don't see how we'd do any better with silver nanoparticles.
Nothing I'm saying is meant to condemn recycling as a concept, by the way. Only to condemn technologies where disposal is dismissed with a shrug and a "idk just recycle it."
> we can't manage to keep that out of the water supply!
AFAIK, the lead in the water supply doesn't come from batteries. It mostly comes from lead pipes. Lead acid battery recycling is one of the more efficient recycling programs out there.
"efficient" and "clean" aren't the same thing, and they never have been.
Recycling lead-acid batteries is extremely efficient. Nearly the entire battery by mass is recovered.
But, it also causes severe lead pollution around recycling sites. Lead acid battery recycling is one of the leading causes of lead poisoning around the world [1]. Estimations vary, but all generally agree that millions of human-years of life have been lost due to lead pollution caused specifically by lead-acid battery recycling. [2]
[1]: https://link.springer.com/chapter/10.1007/978-0-387-77030-7_...
[2]: https://pmc.ncbi.nlm.nih.gov/articles/PMC5990833/
Returning to the original point, recycling anything involving heavy metals is extremely difficult to do without poisoning people. If we can't avoid it with one of the simplest, dumbest battery technologies in regular use today, I don't see how we're going to avoid it with a battery technology involving heavy metal nanoparticles.